date | Pair 1 | sets | Pair 2 | set 1 | set 2 | set 3 |
| D Hantuchova / Andrea Hlavackova | SVK | CZE | 1 | bye |
--- --.06.13 | L Dominguez Lino / G Muguruza | ESP | ESP | | 2-0 | S Soler-Espinosa / C Suarez Navarro | ESP | ESP | | 7-5 | 6-4 | |
--- --.06.13 | D Cibulkova / Arantxa Parra Santonja | SVK | ESP | | 2-0 | N Bratchikova / O Govortsova | --- | BLR | 4 | 6-4 | 6-3 | |
--- --.06.13 | Demi Schuurs / A Van Der Meet | NED | NED | WC | 2-0 | M Melnikova / P Pekhova | --- | BLR | | 6-3 | 6-3 | |
--- --.06.13 | R Hogenkamp / Arantxa Rus | NED | NED | | 2-1 | S Klemenschits / R Oprandi | AUT | SUI | | 6-2 | 3-6 | 10-4 |
--- --.06.13 | Shuko Aoyama / M Moulton-Levy | JPN | USA | 3 | 2-0 | N Frankova / M Kondratieva | CZE | | | 7-5 | 6-2 | |
--- --.06.13 | S Arvidsson / Johanna Larsson | SWE | SWE | | 2-0 | E Cabeza Candela / A Cadantu | ESP | ROU | | 7-5 | 6-0 | |
--- --.06.13 | Irina Camelia Begu / A Medina Garrigues | ROU | ESP | 2 | 2-1 | Kiki Bertens / Michaella Krajicek | NED | NED | | 7-62 | 5-7 | 10-7 |