| Round Robin | w | l | pf | pa | ratio | | 1. Soviet Union | 8 | 1 | 26: | 8 | 1.423 | | 2. Japan | 7 | 2 | 24: | 6 | 1.667 | | 3. Czechoslovakia | 7 | 2 | 22: | 15 | 1.089 | | 4. East Germany | 6 | 3 | 22: | 12 | 1.201 | | 5. Poland | 6 | 3 | 18: | 11 | 1.320 | | 6. Bulgaria | 4 | 5 | 16: | 17 | 0.984 | | 7. United States | 4 | 5 | 15: | 18 | 0.925 | | 8. Belgium | 2 | 7 | 6: | 24 | 0.587 | | 9. Brazil | 1 | 8 | 8: | 25 | 0.587 | | 10.Mexico | 0 | 9 | 6: | 27 | 0.572 |
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| Team | So | Ja | Cz | Ea | Po | Bu | Un | Be | Br | Me | | Soviet Union | --- | 3:1 | 3:0 | 3:2 | 3:0 | 3:0 | | 3:0 | 3:1 | 3:1 | | Japan | | --- | | 3:0 | 3:0 | 3:0 | 3:0 | 3:0 | 3:0 | 3:0 | | Czechoslovakia | | 3:2 | --- | 3:2 | | 3:2 | 3:1 | 3:0 | 3:2 | 3:0 | | East Germany | | | | --- | 3:0 | 3:2 | 3:0 | 3:0 | 3:1 | 3:0 | | Poland | | | 3:1 | | --- | 3:0 | 3:0 | 3:0 | 3:0 | 3:1 | | Bulgaria | | | | | | --- | 3:2 | 3:0 | 3:0 | 3:0 | | United States | 3:2 | | | | | | --- | 3:0 | 3:0 | 3:1 | | Belgium | | | | | | | | --- | 3:1 | 3:2 | | Brazil | | | | | | | | | --- | 3:1 | | Mexico | | | | | | | | | | --- |
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| date | time | team 1 | score | team 2 | pts | g1 | g2 | g3 | g4 | g5 | | 13.10 | 10:00 | Japan | 3-0 | Poland | 45-30 | 15-9 | 15-11 | 15-10 | | | 13.10 | 10:00 | Belgium | 3-1 | Brazil | 55-42 | 15-7 | 16-14 | 9-15 | 15-6 | | | 13.10 | 17:00 | Bulgaria | 3-0 | Mexico | 45-19 | 15-9 | 15-4 | 15-6 | | | 13.10 | 17:00 | United States | 3-2 | Soviet Union | 66-56 | 11-15 | 15-10 | 10-15 | 15-10 | 15-6 | | 13.10 | 19:00 | Czechoslovakia | 3-2 | East Germany | 74-65 | 15-12 | 15-17 | 14-16 | 15-11 | 15-9 | | 16.10 | 10:00 | Bulgaria | 3-0 | Belgium | 45-16 | 15-10 | 15-1 | 15-5 | | | 16.10 | 12:00 | Czechoslovakia | 3-1 | United States | 55-29 | 15-0 | 10-15 | 15-7 | 15-7 | | | 16.10 | 17:00 | Poland | 3-1 | Mexico | 52-32 | 15-10 | 7-15 | 15-4 | 15-3 | | | 16.10 | 17:00 | Soviet Union | 3-1 | Brazil | 56-35 | 11-15 | 15-2 | 15-9 | 15-9 | | | 16.10 | 19:00 | Japan | 3-0 | East Germany | 45-27 | 15-6 | 15-8 | 15-13 | | | 17.10 | 10:00 | East Germany | 3-0 | Mexico | 45-14 | 15-3 | 15-5 | 15-6 | | | 17.10 | 10:00 | Soviet Union | 3-0 | Bulgaria | 45-29 | 15-10 | 15-9 | 15-10 | | | 17.10 | 12:00 | Poland | 3-0 | Belgium | 45-19 | 15-6 | 15-5 | 15-8 | | | 17.10 | 17:00 | United States | 3-0 | Brazil | 45-29 | 15-12 | 15-7 | 15-10 | | | 17.10 | 19:00 | Czechoslovakia | 3-2 | Japan | 50-65 | 2-15 | 3-15 | 15-12 | 15-12 | 15-11 | | 19.10 | 10:00 | Japan | 3-0 | Mexico | 45-15 | 15-1 | 15-3 | 15-11 | | | 19.10 | 10:00 | Bulgaria | 3-2 | United States | 65-66 | 10-15 | 17-15 | 7-15 | 15-7 | 16-14 | | 19.10 | 12:00 | Soviet Union | 3-0 | Poland | 45-29 | 15-9 | 15-10 | 15-10 | | | 19.10 | 17:00 | Czechoslovakia | 3-2 | Brazil | 71-61 | 15-12 | 15-10 | 13-15 | 13-15 | 15-9 | | 19.10 | 19:00 | East Germany | 3-0 | Belgium | 45-15 | 15-1 | 15-7 | 15-7 | | | 20.10 | 12:00 | Japan | 3-0 | Belgium | 45-14 | 15-5 | 15-5 | 15-4 | | | 20.10 | 12:00 | Bulgaria | 3-0 | Brazil | 48-27 | 15-8 | 18-16 | 15-3 | | | 20.10 | 17:00 | Czechoslovakia | 3-0 | Mexico | 45-26 | 15-10 | 15-8 | 15-8 | | | 20.10 | 17:00 | Poland | 3-0 | United States | 45-18 | 15-5 | 15-5 | 15-8 | | | 20.10 | 19:00 | Soviet Union | 3-2 | East Germany | 67-55 | 10-15 | 15-9 | 15-11 | 12-15 | 15-5 | | 21.10 | 10:00 | Czechoslovakia | 3-2 | Bulgaria | 59-53 | 15-7 | 10-15 | 15-9 | 4-15 | 15-7 | | 21.10 | 12:00 | Belgium | 3-2 | Mexico | 66-49 | 15-11 | 5-15 | 13-15 | 18-16 | 15-2 | | 21.10 | 12:00 | East Germany | 3-0 | United States | 45-30 | 15-8 | 15-12 | 15-10 | | | 21.10 | 17:00 | Poland | 3-0 | Brazil | 45-23 | 15-12 | 15-4 | 15-7 | | | 21.10 | 19:00 | Soviet Union | 3-1 | Japan | 49-50 | 4-15 | 15-13 | 15-9 | 15-13 | | | 23.10 | 10:00 | Poland | 3-0 | Bulgaria | 45-18 | 15-3 | 15-5 | 15-10 | | | 23.10 | 10:00 | Soviet Union | 3-1 | Mexico | 56-33 | 15-5 | 15-8 | 11-15 | 15-5 | | | 23.10 | 12:00 | Japan | 3-0 | United States | 45-24 | 15-5 | 15-8 | 15-11 | | | 23.10 | 12:00 | East Germany | 3-1 | Brazil | 59-48 | 15-13 | 15-7 | 14-16 | 15-12 | | | 23.10 | 19:00 | Czechoslovakia | 3-0 | Belgium | 45-16 | 15-0 | 15-4 | 15-12 | | | 24.10 | 10:00 | Japan | 3-0 | Brazil | 45-31 | 15-8 | 15-11 | 15-12 | | | 24.10 | 10:00 | East Germany | 3-2 | Bulgaria | 63-58 | 15-11 | 8-15 | 15-10 | 10-15 | 15-7 | | 24.10 | 12:00 | United States | 3-1 | Mexico | 59-46 | 14-16 | 15-10 | 15-9 | 15-11 | | | 24.10 | 17:00 | Poland | 3-1 | Czechoslovakia | 57-36 | 15-5 | 15-3 | 12-15 | 15-13 | | | 24.10 | 19:00 | Soviet Union | 3-0 | Belgium | 45-10 | 15-2 | 15-3 | 15-5 | | | 25.10 | 10:00 | Japan | 3-0 | Bulgaria | 45-18 | 15-7 | 15-6 | 15-5 | | | 25.10 | 12:00 | United States | 3-0 | Belgium | 46-28 | 15-4 | 16-14 | 15-10 | | | 25.10 | 17:00 | Brazil | 3-1 | Mexico | 47-29 | 14-16 | 15-6 | 17-15 | 15-8 | | | 25.10 | 19:00 | East Germany | 3-0 | Poland | 45-23 | 15-11 | 15-6 | 15-6 | | | 25.10 | 20:00 | Soviet Union | 3-0 | Czechoslovakia | 45-19 | 15-7 | 15-4 | 15-8 | |
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| Tunisia withdrew in the spring of 1968 | | Romania withdrew in the last moment. |
| team | replaced | from | pl | | Bulgaria | Tunisia | World Men 1966 | 7th | | Belgium | Romania | invitation |
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| 1. Soviet Union | | Eduard Sibiryakov | | Yury Poyarkov | | Georgy Mondzolevsky | | Valery Kravchenko | | Vladimir Belyayev | | Yevgeny Lapinsky | | Ivans Bugajenkovs | | Antropovs Oļegs | | Vasilijus Matuševas | | Viktor Mikhalchuk | | Boris Tereshchuk | | Vladimir Ivanov |
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| 2. Japan | | Masayuki Minami | | Katsutoshi Nekoda | | Mamoru Shiragami | | Isao Koizumi | | Kenji Kimura | | Yasuaki Mitsumori | | Jungo Morita | | Tadayoshi Yokota | | Seiji Oko | | Tetsuo Sato | | Kenji Shimaoka |
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| 3. Czechoslovakia | | Bohumil Golián | | Antonín Procházka | | Petr Kop | | Jiří Svoboda | | Josef Musil | | Lubomír Zajíček | | Josef Smolka | | Vladimír Petlák | | František Sokol | | Zdeněk Groessl | | Pavel Schenk | | Drahomír Koudelka |
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| 4. East Germany | | Arnold Schulz | | Eckehard Pietzsch | | Eckhard Tielscher | | Horst Peter | | Freiwald Jürgen | | Kessel Jürgen | | Manfred Heine | | Rainer Tscharke | | Rudi Schumann | | Siegfried Schneider | | Walter Toussaint | | Wolfgang Webner |
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| 5. Poland | | Aleksander Skiba | | Edward Skorek | | Hubert Wagner | | Jerzy Szymczyk | | Romuald Paszkiewicz | | Stanisław Gościniak | | Stanisław Zduńczyk | | Tadeusz Siwek | | Wojciech Rutkowski | | Zbigniew Jasiukiewicz | | Zbigniew Zarzycki | | Zdzisław Ambroziak |
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| 6. Bulgaria | | Aleksandar Aleksandrov | | Aleksandar Trenev | | Angel Koritarov | | Dimitar Karov | | Dimitar Zlatanov | | Dinko Atanasov | | Gramen Prinov | | Kiril Slavov | | Milcho Milev | | Petar Krachmarov | | Stoyan Stoyanov | | Zdravko Simeonov |
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| 7. United States | | John Alstrom | | Mike Bright | | Winthrop Davenport | | Horace Duke | | Tom Haine | | John Henn | | Robert May | | Daniel Patterson | | Larry Rundle | | Jon Stanley | | Rudy Suwara | | Pedro Velasco, Jr. | | Women's Volleyball |
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| 8. Belgium | | Benno Saelens | | Bernard Vaillant | | Berto Poosen | | Fernand Walder | | Hugo Huybrechts | | Jozef Mol | | Leo Dierckx | | Paul Mestdagh | | Roger Maes | | Roger Vandergoten | | Ronald Vandewal | | Willem Bossaerts |
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| 9. Brazil | | Antônio Carlos Moreno | | Feitosa | | Décio de Azevedo | | Gerson Schuck | | João Jens | | Jorge Souza | | José da Costa | | Marco Antônio Volpi | | Dunlop Mário | | Paulo Peterle | | Pinheiro Sérgio | | Victor Borges |
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| 10.Mexico | | Antonio Barbet | | Carlos Aguirre | | Carlos Barron | | Osuna César | | Eduardo Jiménez | | Eduardo Sixtos | | Francisco González | | Jesús Loya | | Joël Calva | | Juan Manuel Duran | | Leopoldo Reyna | | Luis Martell |
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